Low optical dosage heating-reduced viscosity for fast and large-scale cleanup of spilled crude oil by reduced graphene oxide melamine nanocomposite adsorbents
Guangqiao Xu, Li Zhang, Wei Yu, Zhiguo Sun, Jie Guan, Jiaoxia Zhang, Jing Lin, Juying Zhou, Jincheng Fan, Vignesh Murugadoss, Zhanhu Guo
Abstract
Abstract Heating under low solar radiation intensity is demonstrated to facilitate the cleaning of crude oil by the hydrophobic nanocomposite adsorbents of reduced graphene oxide (RGO) melamine sponge (MS@RGO) foams. The heat generated by the irradiation reduces the viscosity of the crude oil, and consequently increases the oil-diffusion coefficient of the pores of the MS@RGO foams and speeds up the oil-sorption rate. Even under a solar radiation intensity as low as 2 kW m −2 , the temperature of crude oil rapidly rises to 68 °C or higher within 10 min. It only takes 29 s to completely absorb 6 g of crude oil at 60 °C by three tiny pieces of MS@RGO foam. This work makes better use of the excellent photothermal conversion characteristics of crude oil, and its photothermal conversion mechanism under simulated solar radiation is also discussed. This methodology can be adopted to clean up viscous crude oil or extract other chemicals effectively at a large scale, and provides a complete solution for the cleanup of crude oil in the sea or on the beach for actual engineering applications.