Nickel‐Catalyzed Amination of (Hetero)aryl Halides Facilitated by a Catalytic Pyridinium Additive

Abstract

Abstract An efficient and operationally simple Ni‐catalyzed amination protocol has been developed. This methodology features a simple Ni II salt, an organic base and catalytic amounts of both a pyridinium additive and Zn metal. A diverse number of (hetero)aryl halides were coupled successfully with primary and secondary alkyl amines, and anilines in good to excellent yields. Similarly, benzophenone imine gave the corresponding N ‐arylation product in an excellent yield.

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