BODIPY-based regioisomers and a donor–acceptor rotor as organic photosensitizers for maximizing singlet oxygen quantum yields and for the photooxidation of thioanisole
Sushil Sharma, Sakshi Chawla, Vidushi Gupta, Arijit K. De, Sanchita Sengupta
Abstract
BODIPY regioisomers and a rotor T-ADA showed singlet oxygen quantum yields of up to 77% due to the multifaceted generation of triplet states as confirmed experimentally and were utilized for the efficient photooxidation of thioanisole.
Topics & Concepts
ThioanisoleSinglet oxygenPhotochemistryBODIPYChemistryAcceptorStructural isomerSinglet stateOxygenPorphyrinRotor (electric)Excited stateOrganic chemistryCatalysisFluorescencePhysicsNuclear physicsQuantum mechanicsCondensed matter physicsLuminescence and Fluorescent MaterialsMolecular Sensors and Ion DetectionPorphyrin and Phthalocyanine Chemistry