Introducing sterically demanding substituents and π–π-interactions into [Cu(P^P)(N^N)]<sup>+</sup> complexes
Marco Meyer, Alessandro Prescimone, Edwin C. Constable, Catherine E. Housecroft
Abstract
By introducing sterically demanding substituents in the N^N ligand in [Cu(P^P)(N^N)] + , solid-state photoluminescence quantum yields of up to 72% have been achieved.
Topics & Concepts
Steric effectsPhotoluminescenceLigand (biochemistry)ChemistrySolid-stateQuantum chemicalStereochemistryCrystallographyMedicinal chemistryMoleculeMaterials scienceOrganic chemistryPhysical chemistryReceptorBiochemistryOptoelectronicsMetal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes