The importance of spodium bonds, H-bonds and π-stacking interactions in the solid state structures of four zinc complexes with tetradentate secondary diamine ligands
Puspendu Middya, Mainak Karmakar, Rosa M. Gomila, Michael G. B. Drew, Antonio Frontera, Shouvik Chattopadhyay
Abstract
The study is devoted to the analysis of the Zn⋯O contacts established between the square-pyramidal Zn metal centers and the co-crystallized DMF and DMSO molecules.
Topics & Concepts
ChemistryStackingDiamineSolid-stateZincCrystallographyStereochemistryPolymer chemistryOrganic chemistryPhysical chemistryCrystallography and molecular interactionsMetal complexes synthesis and propertiesMetal-Organic Frameworks: Synthesis and Applications