Emerging Organometallic Methods for the Synthesis of C‐Branched (Hetero)aryl, Alkenyl, and Alkyl Glycosides: C−H Functionalization and Dual Photoredox Approaches
Juba Ghouilem, Morgane de Robichon, Franck Le Bideau, Angélique Ferry, Samir Messaoudi
Abstract
Transition-metal-catalyzed C-H functionalization and photoredox nickel dual catalysis have emerged as innovative and powerful avenues for the synthesis of C-branched glycosides. These two concepts have been recently established and provide efficient and mild methods for accessing a series of valuable complex C-branched glycosides of great interest. Herein, recent developments in the synthesis of C-branched aryl/alkenyl/alkyl glycosides through these two approaches are highlighted.
Topics & Concepts
Surface modificationAlkylArylGlycosidePhotoredox catalysisChemistryCombinatorial chemistryCatalysisTransition metalDual functionOrganic chemistryComputer sciencePhotocatalysisPhysical chemistryContouringComputer graphics (images)Catalytic C–H Functionalization MethodsSynthesis and Catalytic ReactionsSulfur-Based Synthesis Techniques