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Benchmark of <i>GW</i> Methods for Core-Level Binding Energies

Jiachen Li, Ye Jin, Patrick Rinke, Weitao Yang, Dorothea Golze

2022Journal of Chemical Theory and Computation71 citationsDOIOpen Access PDF

Abstract

calculations based on an optimized hybrid functional starting point, and a Hedin shift in the Green's function. While all methods reproduce the experimental relative binding energies well, the eigenvalue self-consistent schemes and the Hedin shift yield with mean absolute errors <0.2 eV the best results.

Topics & Concepts

Benchmark (surveying)Eigenvalues and eigenvectorsFunction (biology)Binding energyComputationPhysicsComputational physicsAtomic physicsMathematicsAlgorithmQuantum mechanicsGeodesyEvolutionary biologyGeographyBiologyAdvanced Chemical Physics StudiesElectron and X-Ray Spectroscopy TechniquesX-ray Spectroscopy and Fluorescence Analysis
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