Pressing matter: why are ionic liquids so viscous?
Frederik Philippi, Daniel Rauber, Kira L. Eliasen, Nathalie Bouscharain, Kristine Niss, Christopher W. M. Kay, Tom Welton
Abstract
collective and long-range mechanisms. To distinguish between these two theories, we compared an ionic liquid with its uncharged, isoelectronic, isostructural molecular mimic. We measured the viscosity of the molecular mimic at high pressure to emulate the high densities in ionic liquids, which result from the Coulomb interactions in the latter. We were thus able to reveal that the relative contributions of coulombic compaction and the charge network interactions are of similar magnitude. We therefore suggest that the optimisation of the viscosity in room temperature ionic liquids must follow a dual approach.
Topics & Concepts
Ionic liquidPressingIonic bondingChemistryChemical engineeringMaterials scienceChemical physicsIonComposite materialOrganic chemistryEngineeringCatalysisIonic liquids properties and applicationsMaterial Dynamics and PropertiesPhase Equilibria and Thermodynamics