Experimental and Computational Insight into the Mechanism of NO Binding to Ferric Microperoxidase. The Likely Role of Tautomerization to Account for the pH Dependence
Maria Oszajca, Gabriela Drabik, Mariusz Radoń, Alicja Franke, Rudi van Eldik, Grażyna Stochel
Abstract
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Topics & Concepts
ChemistryTautomerMechanism (biology)Computational chemistryFerricChemical physicsStereochemistryInorganic chemistryEpistemologyPhilosophyMetal-Catalyzed Oxygenation MechanismsPorphyrin and Phthalocyanine ChemistryPhotosynthetic Processes and Mechanisms