A tetraazanaphthalene radical-bridged dysprosium single-molecule magnet with a large coercive field
Florian Benner, Saroshan Deshapriya, Selvan Demir
Abstract
prior computations, but is within this study for the first time experimentally confirmed. In sum, highly-tunable azaacene radicals have immense potential not only for radical-containing SMMs but for high-performance magnetic materials at large.
Topics & Concepts
LanthanideDiamagnetismMagnetChemistryCoercivityAtomic orbitalDysprosiumValence (chemistry)ElectronegativityOpen shellChemical physicsCovalent bondMetathesisLigand (biochemistry)Inductive couplingDimerCrystallographyIonCondensed matter physicsMagnetic susceptibilityMagnetic fieldBridging ligandIntramolecular forceMagnetic hysteresisMaterials scienceValence bond theoryRadicalLigand field theoryOrbital hybridisationDelocalized electronField (mathematics)Molecular orbitalSpin (aerodynamics)HysteresisCoupling (piping)Salt metathesis reactionDeprotonationValence electronNuclear magnetic resonanceMagnetism in coordination complexesQuantum and electron transport phenomenaPorphyrin and Phthalocyanine Chemistry