V-shape Tröger's base-based organic solvent nanofiltration membranes for fast and precise molecular separation
Chenglong Yang, Shuqi Liu, Qiyue Zhao, Xinfan Zhang, Zhenggong Wang, Feng Zhang, Jian Jin
Abstract
Organic solvent nanofiltration (OSN) membranes with precise molecular-sieving performance have become increasingly important in chemical and pharmaceutical industries, desiring superior membranes with both high permeability and selectivity. Herein, the V-shape Tröger's base (TB) structure is incorporated in the polyamide network to engineer microporosity as well as the molecular-sieving performance of the thin-film composite (TFC) polyamide membrane for organic solvent nanofiltration (OSN). The TFC membrane containing the TB structure features a rigid and contorted chain structure, which affords high and stable methanol permeability in OSN applications. Furthermore, the H-bond interaction between the H of amide groups and N in TB reinforces the interchain interaction, endowing the membrane with a precise selectivity to organic solutes. The as-prepared TFC membrane demonstrated high methanol permeance of 16.6 L m −2 h −1 bar −1 and sieving performance to organic molecules with molecular weight cut-off (MWCO) down to 349 Da. Furthermore, the membrane demonstrates shape selectivity for organic solutes, exploiting the fine microporous structure. This study may provide insights into the molecular design of TFC membranes by finely tuning the molecular features for precise solute separations.