Strong NIR-II Magneto-Optical Activity of a Chiral Sm<sub>15</sub>Cu<sub>54</sub> Cage
Jianan Chen, Kaixin Huang, Pei‐Ming Cheng, Ming‐Qiang Qi, Han Xu, Jiaye Chen, Yingying Duan, Xiang‐Jian Kong, Lan-Sun Zheng, La‐Sheng Long
Abstract
The magneto-optical response of chiral materials holds significant potential for applications in physics, chemistry, and biology. However, exploration of the near-infrared (NIR) magneto-optical response remains limited. Herein, we report the synthesis and strong NIR-II magneto-optical activity of three pairs of chiral 3 d– 4 f clusters of R/S -Ln 15 Cu 54 (Ln = Sm, Gd, and Dy). Structural analysis reveals that R/S -Ln 15 Cu 54 features a triangular prism cage with C 3 symmetry. Interestingly, magnetic circular dichroism (MCD) spectra exhibit remarkable magneto-optical response in the NIR-II region, driven by the f–f transition. The maximum g -factor of R/S -Sm 15 Cu 54 reaches 5.5 × 10 –3 T –1 around 1300–1450 nm, surpassing values associated with Dy III and Cu II ions. This remarkable NIR-II magneto-optical activity may be attributed to strong magnetic-dipole-allowed f–f transitions and helix chirality of the structure. This work not only presents the largest Ln-Cu clusters to date but also demonstrate the key role of magnetic-dipole-allowed transitions on magneto-optical activity.