Photoinduced Pyridine N‐oxides Catalyzed Carbon Radical Generation from Alkylboronic Acids
Cristina Ascenzi‐Pettenuzzo, Juliet Nganda, Yongming Deng
Abstract
Abstract Herein we report a protocol for the generation of alkyl carbon radicals from alkylboronic acids wherein photoexcited 4‐nitropyridine N‐oxide biradical features a catalyst to promote the nucleo‐homolytic substitution of boronic acids. With a wide range of readily available aliphatic boronic acids, including methyl boronic acid, the developed catalytic system demonstrates broad applicability for alkylation, amination, and cyanation.
Topics & Concepts
ChemistryCyanationCatalysisHomolysisAminationRadicalBoronic acidOrganic chemistryAlkylationAlkylCombinatorial chemistryPyridineRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsFluorine in Organic Chemistry