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Manipulating the carrier concentration and phase transition via Nb content in SrTiO3

Zhe Zhang, Peihua Qian, Xingming Yang, Baixi Wu, H. L. Cai, F. M. Zhang, X. S. Wu

2022Scientific Reports18 citationsDOIOpen Access PDF

Abstract

Abstract SrTiO 3 is a model of the perovskite-like compounds for structural transition which inducing the intriguing physical properties around the critical phase transition temperature T AFD (antiferrodistortive, abbrev. as AFD). Here we report that the electrical transport behavior is a new way to quantify Nb concentration for Nb-doped SrTiO 3 . The lattice parameter (c), phase transition temperature (T AFD ), and the carrier concentration (n) of SrTiO 3 may be manipulated by niobium doping. T AFD increases with increasing the niobium content in a rate of about 30 K per (wt%, i.e. niobium element’s weight verses total weight) niobium and n in a rate of about 2.5 $$\times$$ <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mo>×</mml:mo></mml:math> 10 20 /cm 3 per (wt%) niobium.

Topics & Concepts

NiobiumPhase transitionMaterials scienceTransition temperatureLattice (music)Electrical resistivity and conductivityPhase (matter)Lattice constantPhase diagramChemical physicsAnalytical Chemistry (journal)ThermodynamicsTransition metalCrystallographyInorganic chemistryChemistryCondensed matter physicsSuperconductivityPhysical chemistrySuperconducting transition temperatureFree carrierElectronic and Structural Properties of OxidesFerroelectric and Piezoelectric MaterialsMachine Learning in Materials Science
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