Sustainable nanocomposite films based on SiO <sub>2</sub> and biodegradable poly(3-hydroxybutyrate- <i>co</i> -3-hydroxyhexanoate) (PHBH) for food packaging
Yujuan Qiu, Jirui Fu, Binqing Sun, Xiaojun Ma
Abstract
Abstract Sustainable nanocomposites with transparent, biodegradable, and enhanced mechanical and barrier properties were prepared by the incorporation of SiO 2 into poly(3-hydroxybutyrate- co -3-hydroxyhexanoate) (PHBH) films and subsequent solvent casting. The crystallinity of composites could be increased by 67% with appropriate contents of SiO 2 , which proved that SiO 2 were effective nucleating agents for PHBH. And it was worth mentioning that the contributions of SiO 2 to the crystallization and thermal stability of composites are proved effectively by Avrami relationship and Horowitz and Metzger method. More importantly, compared with PHBH, it had not only an enhancement about 40% and 60% on the tensile strength and elastic modulus, respectively, but also half the reduction of the moisture and oxygen permeability which were much higher than the values of conventional plastics. The above, in conjunction with the low migration rate measured in food substitutes, illustrated unambiguously that the nanocomposites might be suitable for potential application in food packaging.