Photocatalytic one-pot alkylation of nitrobenzene with benzyl alcohol for the precise synthesis of <i>N</i>-benzylideneaniline over F-doped Bi<sub>2</sub>MoO<sub>6</sub> nanosheets
Guangcheng Zou, Rui Cao, Conghui Cui, Yuqiang Luo, Chen Huang, Xinwei Cui, Zhiwen Wang, Yujie Song
Abstract
Selective chemisorption and activation of benzyl alcohol and nitrobenzene on F 0.04 -BMO-NSs via interface coordination Bi 3+ (Mo 6+ )⋯OH–C– and Mo 5+ ⋯O 2 N. Hydrogen transfer takes place from the alcohol to nitrobenzene precisely forming N -benzylideneaniline.
Topics & Concepts
NitrobenzeneBenzyl alcoholAlkylationCatalysisAlcoholChemistryPhotocatalysisDopingChemisorptionPhotochemistryHydrogenMedicinal chemistryMaterials scienceOrganic chemistryOptoelectronicsAdvanced Photocatalysis TechniquesChemical Synthesis and ReactionsCovalent Organic Framework Applications