Ag-Catalyzed ring-opening of tertiary cycloalkanols for C–H functionalization of cyclic aldimines
Jingjing Wang, Xue Liu, Ziyan Wu, Feng Li, Mingliang Zhang, Yiman Mi, Junhao Wei, Yao Zhou, Lantao Liu
Abstract
We firstly describe a silver-catalyzed direct C-H functionalization of cyclic aldimines with cyclopropanols and cyclobutanols via a radical-mediated C-C bond cleavage strategy. The desired products were generated in decent yields with wide substrate scope under mild reaction conditions. In addition, a gram-scale reaction and synthetic transformation of the product were performed.
Topics & Concepts
AldimineCatalysisSurface modificationChemistryCleavage (geology)Ring (chemistry)Bond cleavageSubstrate (aquarium)Organic chemistryMaterials scienceFracture (geology)Composite materialPhysical chemistryGeologyOceanographyCatalytic C–H Functionalization MethodsCyclopropane Reaction MechanismsSynthesis and Catalytic Reactions