Ferroelectrovalley in Two-Dimensional Multiferroic Lattices
Jiangyu Zhao, Yangyang Feng, Ying Dai, Baibiao Huang, Yandong Ma
Abstract
Engineering the valley index is essential and highly sought for valley physics, but currently, it is exclusively based on the paradigm of the challenging ferrovalley with spin-orientation reversal under a magnetic field. Here, an alternative strategy, i.e., the so-called ferroelectrovalley, is proposed to tackle the insurmountable spin-orientation reversal, which reverses the valley index with the feasible ferroelectricity. Using symmetry arguments and the tight-binding model, the C 2 z rotation is unveiled to be able to take the place of time reversal for operating the valley index in two-dimensional multiferroic kagome lattices, which enables a ferroelectricity-engineered valley index, thereby generating the concept of a ferroelectrovalley. Based on first-principles calculations, this concept is further demonstrated in the breathing kagome lattice of single-layer Ti 3 Br 8, wherein ferroelectricity couples with the breathing process. These findings open a new direction for valleytronics and 2D materials research.