Layered P3-Type K<sub>0.4</sub>Fe<sub>0.1</sub>Mn<sub>0.8</sub>Ti<sub>0.1</sub>O<sub>2</sub> as a Low-Cost and Zero-Strain Electrode Material for both Potassium and Sodium Storage
Xinyuan Zhang, Dongxu Yu, Zhixuan Wei, Nan Chen, Gang Chen, Zexiang Shen, Fei Du
Abstract
Layered transition metal oxides are ideal Na+/K+ host materials due to their high theoretical capacities and appropriate working potentials, and the pursuit of cost-effective and environmentally friendly alternatives with high energy density and structural stability has remained a hot topic. Herein, we design and synthesize a low-cost and zero-strain cathode material, P3-type K0.4Fe0.1Mn0.8Ti0.1O2, which demonstrates superior properties for both potassium and sodium storage. The cathode delivers a reversible potassium storage capacity of 117 mA h g–1 at 20 mA g–1 and a fast rate capability of 71 mA h g–1 at 1000 mA g–1. In situ X-ray diffraction reveals a solid–solution transition with a negligible volume change of 0.5% upon K+ insertion/deinsertion that ensures long cycling stability over 300 cycles. When the material is employed for sodium storage, a spontaneous ion-exchange process with Na+-containing electrolytes occurs. Thanks to the positive effects of the remaining K+ ions that protect the layered structure from collapse as well as expand the interlayer structure, and the resulting K0.12Na0.28Fe0.1Mn0.8Ti0.1O2 demonstrates a high sodium storage capacity of 160 mA h g–1 and superior cycling stability with capacity retention of 81% after 300 cycles as well as fast kinetics.