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CuCe-Ferrite/TiO2 Nanocomposite as an Efficient Magnetically Separable Photocatalyst for Dye Pollutants Decolorization

Elsayed T. Helmy, Usama A. Soliman, A. M. Elbasiony, Ba-Son Nguyen

2022Topics in Catalysis25 citationsDOIOpen Access PDF

Abstract

Abstract In this work, a magnetically separated photocatalyst with great efficiency CuCe-Ferrite/TiO 2 composite was prepared and characterized by X-ray diffraction (XRD), UV–Vis spectrophotometry, Fourier transformer infra-red spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), high resolution transmission electron microscopy (HR-TEM), energy dispersive X-ray spectroscopy (EDX) and vibrating sample magnetometer (VSM). Single-phase cubic spinel was formed by calcining the prepared sample at a temperature of 550 °C, according to the results. Different concentrations of reactive red 250 (RR250) dye photodegradation was evaluated using different doses of CuCe-ferrite/ TiO 2 and TiO 2 NPs. Higher efficiency of RR250 photodegradation up to 100% was obtained using CuCe-ferrite/ TiO 2 . The photodegradation efficiency was confirmed using chemical oxygen demand (COD) test of both treated and untreated samples. The oxidation process was mostly mediated by photogenerated . O 2− according to scavenger test results. The catalyst possess higher photodegradation efficiency even after regeneration for ten times. Graphical Abstract

Topics & Concepts

PhotodegradationPhotocatalysisMaterials scienceFourier transform infrared spectroscopyScanning electron microscopeFerrite (magnet)NanocompositeCalcinationNuclear chemistryTransmission electron microscopyAnalytical Chemistry (journal)Diffuse reflectance infrared fourier transformCatalysisChemical engineeringChemistryNanotechnologyChromatographyComposite materialOrganic chemistryEngineeringAdvanced Photocatalysis TechniquesCopper-based nanomaterials and applicationsNanomaterials for catalytic reactions
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