Adaptive chirality of achiral tetraphenylethene-based tetracationic cyclophanes with dual responses of fluorescence and circular dichroism in water
Haiyang Zhang, Lin Cheng, Hao Nian, Jiang Du, Tao Chen, Liping Cao
Abstract
2 reaction without using any template. Based on the fluorescence and rotational conformation of the tetraphenylethene units, these water-soluble cyclophanes exhibited adaptive chirality with dual responses of turn-on fluorescence and induced circular dichroism when combined with nucleotides and DNA in water.
Topics & Concepts
Chirality (physics)Circular dichroismFluorescenceDual (grammatical number)ChemistryCrystallographyStereochemistryBiophysicsOpticsPhysicsBiologyChiral symmetryLiteratureNambu–Jona-Lasinio modelQuantum mechanicsArtQuarkDNA and Nucleic Acid ChemistryLuminescence and Fluorescent MaterialsMolecular Sensors and Ion Detection