An [FeIII30] molecular metal oxide
Alice E. Dearle, Daniel J. Cutler, Marco Coletta, Edward Lee, Sourav Dey, Sergio Sanz, Hector W. L. Fraser, Gary S. Nichol, Gopalan Rajaraman, Jürgen Schnack, Leroy Cronin, Euan K. Brechin
Abstract
ions. Mass spectrometry suggests the cluster is formed quickly and remains stable in solution, while magnetic measurements and DFT calculations reveal competing antiferromagnetic exchange interactions.
Topics & Concepts
AntiferromagnetismDissolutionAcetonitrileOxideMetalOctahedronChemistryCluster (spacecraft)Inorganic chemistryTetrahedronAmine gas treatingMetal ions in aqueous solutionCrystallographyIonPhysical chemistryOrganic chemistryCrystal structurePhysicsProgramming languageComputer scienceCondensed matter physicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Organic Frameworks: Synthesis and Applications