Diamond-Like Carbon: A Surface for Extreme, High-Wear Environments
Najib Sharifi, Holly E. Smith, David C. Madden, Tom B. Kehoe, Guizhi Wu, Liuquan Yang, Rebecca J. L. Welbourn, E. G Fernandez, Stuart M. Clarke
Abstract
High Resolution Image Download MS PowerPoint Slide In this study, we present an in-depth characterization of a diamond-like carbon (DLC) film, using a range of techniques to understand the structure and chemistry of the film both in the interior and particularly at the DLC/air surface and DLC/liquid interface. The DLC film is found to be a combination of sp 2 and sp 3 carbon, with significant oxygen present at the surface. The oxygen seems to be present as OH groups, making the DLC somewhat hydrophilic. Quartz-Crystal Microbalance (QCM) isotherms and complementary neutron reflectivity data indicate significant adsorption of a model additive, bis(2-ethylhexyl) sulfosuccinate sodium salt (AOT) surfactant, onto the DLC from water solutions and indicate the adsorbed film is a bilayer. This initial study of the structure and composition of a model surfactant is intended to give a clearer insight into how DLC and additives function as antiwear systems.