Application of response surface methodology for optimization of the test condition of oxygen evolution reaction over La0.8Ba0.2CoO3 perovskite-active carbon composite
Elham Mahmoudi, Elnaz Asghari, Nagihan Çaylak Delibaş, Aligholi Niaei
Abstract
Abstract The Experimental Design was applied to optimize the electrocatalytic activity of La 0.8 Ba 0.2 CoO 3 perovskite oxide/Active Carbon composite material in the alkaline solution for the Oxygen Evolution Reaction. After the preparation of La 0.8 Ba 0.2 CoO 3 , and structural characterizations, the experimental design was utilized to determine the optimal amount of the composite material and testing conditions. The overpotential was defined as the response variable, and the mass ratio of perovskite/active carbon, Potassium hydroxide (KOH) concentration, and Poly(vinylidene fluoride) (PVDF) amount were considered effective parameters. The significance of model terms is demonstrated by P -values less than 0.0500. The proposed prediction model determined the optimal amounts of 0.665 mg of PVDF, a KOH concentration of 0.609 M, and A perovskite/Active Carbon mass ratio of 2.81 with 308.22 mV overpotential (2.27% greater than the actual overpotential). The stability test of the optimized electrode material over 24 h suggests that it could be a good candidate electrocatalyst for OER with reusability potential.