Synthesis and application of thiocarbamates<i>via</i>thiol-dioxazolone modified Lossen rearrangement
Yu Jiang, Ming Li, Shuxin Liu, Rui Li, Yubin Zheng, Wangze Song, Nan Zheng
Abstract
thiol-dioxazolone modified Lossen rearrangement under transition-metal free, additive free, and mild conditions. Polythiocarbamates were further prepared with excellent self-healing and shape-memory properties, showing great potential in the development of functional materials.
Topics & Concepts
ThiocarbamatesChemistryThiolCombinatorial chemistryOrganic chemistrySulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsPolyoxometalates: Synthesis and Applications