Efficient Separation of Propylene from Propane in an Ultramicroporous Cyanide‐Based Compound with Open Metal Sites
Yi Xie, Yanshu Shi, Hui Cui, Rui‐Biao Lin, Banglin Chen
Abstract
Exploring porous materials for selective adsorptive separation of propylene from propane to replace the energy‐intensive cryogenic distillation technologies remains a great challenge due to the similarity of these two gases in physiochemical properties. Herein, an ultramicroporous material, nickel nitroprusside ( Ni‐NP ), with open metal sites (OMS) for the highly efficient separation of propylene from propane under ambient conditions is reported. This material exhibits high C 3 H 6 /C 3 H 8 selectivity of 10.5 and uptake ratio of 1.68, with a remarkable C 3 H 6 uptake capacity of 79.9 cm 3 g −1 . Dispersion‐corrected density functional theory (DFT‐D) calculations reveal that the selective adsorption of C 3 H 6 is attributed to strong host–guest interactions on the OMSs as well as multiple weak hydrogen bonding within the compact pore space. The C 3 H 6 /C 3 H 8 separation performance is validated by breakthrough experiments, showing a high productivity of 2.30 mol kg −1 . This material can be facilely obtained by simple precipitation reaction under ambient conditions, which highlights its scale‐up potential for C 3 H 6 /C 3 H 8 separation.