Infrared characterization of the products and the rate coefficient of the reaction between Criegee intermediate CH<sub>2</sub>OO and HCl
Wei-Che Liang, Pei-Ling Luo, Yuan‐Pern Lee
Abstract
Infrared spectrum of chloromethyl hydroperoxide, the reaction product of Criegee intermediate CH<sub>2</sub>OO with HCl, was obtained. Secondary products CHClO and H<sub>2</sub>O were also observed. The rate coefficient was determined to be 4.8 × 10<sup>−11</sup> cm<sup>3</sup> molecule<sup>−1</sup> s<sup>−1</sup>.
Topics & Concepts
ChemistryInfraredAnalytical Chemistry (journal)MoleculeInfrared spectroscopyPhysical chemistryOrganic chemistryPhysicsOpticsSpectroscopy and Laser ApplicationsAtmospheric Ozone and ClimateSpectroscopy and Quantum Chemical Studies