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Impact of Strain-Induced Crystallization on Fast Crack Growth in Stretched <i>cis</i>-1,4-Polyisoprene Rubber

Ryosuke Osumi, Tomohiro Yasui, Ruito Tanaka, Thanh‐Tam Mai, Hideaki Takagi, Nobutaka Shimizu, Katsuhiko Tsunoda, Shinichi Sakurai, Kenji Urayama

2022ACS Macro Letters23 citationsDOI

Abstract

. The characteristics of the crack-tip strain field are also significantly influenced by the SIC-driven hardening: The crack-tip opening displacement increases with increasing λ at λ < λ* but exhibits an abrupt reduction beyond λ*. The crack-tip singularity and the area of strain increment caused by the crack growth change discontinuously around λ*. The abrupt variations in these crack-tip characteristics result from the considerable differences in the mechanical properties prior to the crack growth between the entirely amorphous state at λ < λ* and the partially crystallized state at λ > λ*.

Topics & Concepts

Materials scienceComposite materialCrack closureCrack tip opening displacementStrain hardening exponentCrack growth resistance curveNatural rubberCrystallizationHardening (computing)ElastomerAmorphous solidShear (geology)Fracture mechanicsCrystallographyLayer (electronics)Organic chemistryChemistryPolymer Nanocomposites and PropertiesPolymer crystallization and propertiesElasticity and Material Modeling
Impact of Strain-Induced Crystallization on Fast Crack Growth in Stretched <i>cis</i>-1,4-Polyisoprene Rubber | Litcius