Litcius/Paper detail

Electrochemical oxidative <i>Z</i>-selective C(sp<sup>2</sup>)–H chlorination of acrylamides

James Harnedy, Mishra Deepak Hareram, Graham J. Tizzard, Simon J. Coles, Louis C. Morrill

2021Chemical Communications22 citationsDOIOpen Access PDF

Abstract

-β-chloroacrylamides in good yields (22 examples, 73% average yield). The orthogonal derivatization of the products was demonstrated through chemoselective transformations and the electrochemical process was performed on gram scale in flow.

Topics & Concepts

ElectrochemistryOxidative phosphorylationChemistryMedicinal chemistryCombinatorial chemistryNuclear chemistryElectrodePhysical chemistryBiochemistryOxidative Organic Chemistry ReactionsRadical Photochemical ReactionsSynthesis and Catalytic Reactions