Structure and bonding in rhodium coordination compounds: a <sup>103</sup>Rh solid-state NMR and relativistic DFT study
Sean T. Holmes, Jasmin Schönzart, Adam Philips, James J. Kimball, Sara Termos, Adam R. Altenhof, Yijue Xu, Christopher A. O’Keefe, Jochen Autschbach, Robert W. Schurko
Abstract
Rh magnetic shielding tensors to understand their relationship to structure and bonding. Finally, we discuss the potential for these experimental and theoretical protocols for investigating a wide range of materials containing the platinum group elements.
Topics & Concepts
RhodiumChemistrySolid-stateRelativistic quantum chemistryCoordination complexState (computer science)CrystallographyPhysical chemistryComputational chemistryAtomic physicsPhysicsCatalysisOrganic chemistryMathematicsAlgorithmMetalAdvanced NMR Techniques and ApplicationsMagnetism in coordination complexesInorganic Chemistry and Materials