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Extended Corey–Chaykovsky reactions: transformation of 2-hydroxychalcones to benzannulated 2,8-dioxabicyclo[3.2.1]octanes and 2,3-dihydrobenzofurans

Alexander A. Fadeev, Антон С. Макаров, Оlga А. Ivanova, Maxim G. Uchuskin, Igor V. Trushkov

2021Organic Chemistry Frontiers18 citationsDOI

Abstract

We report the divergent synthesis of benzannulated 2,8-dioxabicyclo[3.2.1]octanes and 2,3-dihydrobenzofurans using the concept of extended Corey–Chaykovsky reactions.

Topics & Concepts

ChemistryTransformation (genetics)Organic chemistryBiochemistryGeneCyclopropane Reaction MechanismsSynthetic Organic Chemistry MethodsAsymmetric Synthesis and Catalysis