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WhY shape matters: Hydrodynamics of a Y-shaped membraneless electrolyzer

Karl Schoppmann, Hannes Rox, Erik Frense, Frank Rüdiger, Xuegeng Yang, Kerstin Eckert, Jochen Fröhlich

2025Chemical Engineering Journal9 citationsDOIOpen Access PDF

Abstract

A novel Y-shaped membraneless flow-through electrolyzer is introduced to achieve a homogeneous electrochemical reaction across the entire electrode in a cost-efficient cell design with effective product separation. Numerical simulations of the electrolyte flow and electrical current within the already known I- and T-shaped cells motivate the newly proposed Y-shape cell. Furthermore, a new design criterion is developed based on the balance between bubble removal and gas generation. As proof-of-concept experimental results using the Y-shaped electrolyzer are presented, showing homogeneous gas distributions across the electrode and efficient product separation by the electrolyte flow. • Novel design criterion for electrolyzers balancing generation vs removal of bubbles. • New simulation method for flow-through electrolyzers. • New Y-shaped membraneless electrolyzer. • Efficient product separation using the electrolyte flow.

Topics & Concepts

ElectrolysisMaterials scienceChemical engineeringMechanicsChemistryPhysicsEngineeringPhysical chemistryElectrodeElectrolyteHybrid Renewable Energy SystemsFuel Cells and Related MaterialsAdvanced Battery Technologies Research
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