Spectroscopic and reactive characterization of mixed-metal Fe–Cr trimer nodes in metal–organic framework MIL-100
Jacklyn N. Hall, Praveen Bollini
Abstract
Metal–organic framework MIL-100 featuring heterometallic Fe and Cr M 3 O nodes were synthesized; mixing of the metals within the nodes is evidenced using a combination of in situ IR spectroscopy, NO titrations, and CO oxidation kinetics.
Topics & Concepts
Bimetallic stripTrimerReactivity (psychology)TitrationMetal-organic frameworkMetalCharacterization (materials science)KineticsChemistryX-ray photoelectron spectroscopySpectroscopyInorganic chemistryMaterials scienceChemical engineeringPhysical chemistryNanotechnologyDimerOrganic chemistryAdsorptionEngineeringAlternative medicineQuantum mechanicsPhysicsPathologyMedicineMetal-Organic Frameworks: Synthesis and ApplicationsLanthanide and Transition Metal ComplexesMetal complexes synthesis and properties