Litcius/Paper detail

An integrated giant polyoxometalate complex for photothermally enhanced catalytic oxidation

Xiaofei Chen, Guohua Zhang, Bao Li, Lixin Wu

2021Science Advances65 citationsDOIOpen Access PDF

Abstract

atmosphere in water. The conversion reaches about pentaploid of the reaction without NIR radiation. By excluding heating effect from the external heater at the same temperature, about twice as much enhancement, which can be attributed to the sole photothermal action, is still observed. While the catalytic center is shielded by the organic porous layer, the surface cavity allows the integrated catalyst to conduct a selective catalysis by screening the molecules in size over the surface channel.

Topics & Concepts

Photothermal therapyCatalysisPolyoxometalatePhotochemistryMaterials scienceUltravioletPhotothermal effectCationic polymerizationChemical engineeringNanotechnologyChemistryOptoelectronicsOrganic chemistryPolymer chemistryEngineeringPolyoxometalates: Synthesis and ApplicationsAdvanced Photocatalysis TechniquesAdvanced Nanomaterials in Catalysis