Unlocking the potential of self-healing and recyclable ionic elastomers for soft robotics applications
Saul Utrera‐Barrios, N. Steenackers, Seppe Terryn, Pasquale Ferrentino, Raquel Verdejo, Guy Van Assche, Miguel A. López‐Manchado, Joost Brancart, Marianella Hernández Santana
Abstract
In the field of soft robotics, current materials face challenges related to their load capacity, durability, and sustainability. Innovative solutions are required to address these problems beyond conventional strategies, which often lack long-term ecological viability. This study aims to overcome these limitations using mechanically robust, self-healing, and recyclable ionic elastomers based on carboxylated nitrile rubber (XNBR). The designed materials exhibited excellent mechanical properties, including tensile strengths (TS) exceeding 19 MPa and remarkable deformability, with maximum elongations (EB) over 650%. Moreover, these materials showed high self-healing capabilities, with 100% recovery efficiency of TS and EB at 110 °C after 3 to 5 h, and full recyclability, preserving their mechanical performance even after three recycling cycles. Furthermore, they were also moldable and readily scalable. Tendon-driven soft robotic grippers were successfully developed out of ionic elastomers, illustrating the potential of self-healing and recyclability in the field of soft robotics to reduce maintenance costs, increase material durability, and improve sustainability.