Exploiting the radical reactivity of diazaphosphinanes in hydrodehalogenations and cascade cyclizations
Jingjing Zhang, Jin‐Dong Yang, Jin‐Pei Cheng
Abstract
hydrogen-atom transfer from diazaphosphinanes. The radical reactivity of diazaphosphinanes disclosed here differs from their well-established hydridic reactivity, and hence, opens a new avenue for diazaphosphinane applications in organic syntheses.
Topics & Concepts
CascadeReactivity (psychology)ChemistryRadical cyclizationStereochemistryMedicineChromatographyPathologyAlternative medicineCoordination Chemistry and OrganometallicsCatalytic C–H Functionalization MethodsRadical Photochemical Reactions