Effect of intermolecular anionic interactions on spin crossover of two triple-stranded dinuclear Fe(<scp>ii</scp>) complexes showing above room temperature spin transition
S. Athira, Dibya Jyoti Mondal, Shraoshee Shome, Bijoy Dey, Sanjit Konar
Abstract
Two new Fe(ii)-based dinuclear triple helicates [Fe 2 L 3 ] 4+ , displaying near room temperature spin transition have been synthesized and the effect of intermolecular interactions and co-operativity between metal centers on the SCO has been studied.
Topics & Concepts
Spin crossoverIntermolecular forceSpin (aerodynamics)ChemistryCrystallographyMaterials sciencePhysicsMoleculeOrganic chemistryThermodynamicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies