Hydrogen bond system generated by nitroamino rearrangement: new character for designing next generation energetic materials
Lu Hu, Richard J. Staples, Jean’ne M. Shreeve
Abstract
A new hydrogen bond system is formed by the transfer of a proton from nitroamino to form nitroimino. The proton and the oxygen in nitroimino form an intramolecular hydrogen bond and two intermolecular hydrogen bonds that shorten the distance between molecules both vertically and horizontally leading to higher density.
Topics & Concepts
Intermolecular forceCharacter (mathematics)Hydrogen bondMoleculeHydrogenChemistrySensitivity (control systems)Chemical physicsComputational chemistryMaterials scienceNanotechnologyPhotochemistryOrganic chemistryEngineeringMathematicsGeometryElectronic engineeringEnergetic Materials and CombustionCrystallography and molecular interactionsThermal and Kinetic Analysis