Electrocatalytic study of NiO-MOF with activated carbon composites for methanol oxidation reaction
Saadia Hanif, Naseem Iqbal, Tayyaba Nооr, Neelam Zaman, K. Vignarooban
Abstract
Abstract In this work, the methanol oxidation reaction is investigated on Ni based metal organic frameworks (MOF) and its composites with biomass derived activated carbon. NiO-MOF and composites with activated carbon were synthesized using hydrothermal method. SEM, EDX, and XRD, FTIR, TGA techniques were used for characterization of composites. The electrochemical activity of catalysts for oxidation of methanol was tested using cyclic voltammetry (CV) in 1 M KOH and 3 M CH 3 OH on glassy carbon electrode in three electrode setup. The electrochemical performance shows the effect of activated carbon concentration on methanol oxidation. The electro-oxidation catalyzed by NiO-MOF with activated carbon (40 mg) composite exhibits a peak current density of 182.72 mA/cm 2 at 0.89 V potential with a scan rate of 50 mV/s making it a potential catalyst for electrocatalysis of methanol.