Enhancing catalytic alkane hydroxylation by tuning the outer coordination sphere in a heme-containing metal–organic framework
David Z. Zee, T. David Harris
Abstract
nodes, the acetylated framework oxidizes cyclohexane with a yield of 68(8)%, 2.6-fold higher than in the hydroxylated framework, and an alcohol/ketone ratio of 5.6(3).
Topics & Concepts
HydroxylationCatalysisHemeCoordination sphereChemistryMetal-organic frameworkAlkaneMetalCombinatorial chemistryAcetylationStereochemistryPhotochemistryOrganic chemistryBiochemistryEnzymeAdsorptionGeneMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms