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2D metal–organic frameworks bearing butterfly-shaped metal-bis(dithiolene) linkers from dithiol-functionalized benzenedicarboxylic acid

Hao Zhong, Zhixin Jiang, Jieying Hu, Lai‐Hon Chung, Jun He

2024Chemical Communications10 citationsDOI

Abstract

2D metal-bis(dithiolene) frameworks can be achieved easily either by a stepwise protocol using a butterfly-shaped intermediate or by direct assembly using transition metal ions and 1,4-dicarboxylbenzene-2,3-dithiol.

Topics & Concepts

DithiolMetalTransition metalPolymer chemistryMetal ions in aqueous solutionChemistryMaterials scienceOrganic chemistryCatalysisOrganic and Molecular Conductors ResearchMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexes
2D metal–organic frameworks bearing butterfly-shaped metal-bis(dithiolene) linkers from dithiol-functionalized benzenedicarboxylic acid | Litcius