An oxygen-coordinated molybdenum single atom catalyst for efficient electrosynthesis of ammonia
Jing Geng, Shengbo Zhang, Hui Xu, Guozhong Wang, Haimin Zhang
Abstract
Electrochemical nitrogen (N2) reduction has been regarded as a promising strategy for artificial ammonia (NH3) production under ambient conditions. Herein, we report the fabrication of molybdenum (Mo) single atoms anchored on activated carbon (Mo-SAs/AC) for the electrochemical N2 reduction to NH3. The surface-rich oxygen functional groups of activated carbon can effectively capture the Mo precursor, and concurrently act as the coordination sites to anchor Mo single atoms by forming Mo-Ox bonds. As a result, the Mo-SAs/AC as an electrocatalyst shows high activity toward the N2 reduction reaction (NRR), affording an NH3 yield rate of 2.55 ± 0.31 mg h-1 mgMo-1 and a faradaic efficiency (FE) of 57.54 ± 6.98% at -0.40 V (vs. RHE) in 0.1 M Na2SO4 electrolyte with good stability and durability. The constructed Mo-Ox sites are responsible for high NRR activity of Mo-SAs/AC.