Norcorroles as antiaromatic π-electronic systems that form dimension-controlled assemblies
S. Ishikawa, Kazuhisa Yamasumi, Shinya Sugiura, Shunsuke Sato, Go Watanabe, Yun Hee Koo, Shu Seki, Yuya Bando, Yohei Haketa, Hiroshi Shinokubo, Hiromitsu Maeda
Abstract
the interactions between the antiaromatic systems formed for the butoxy and dodecyloxy derivatives in the single-crystal and LC states, respectively. In particular, the LC state exhibited discotic columnar structures comprising triple deckers to exhibit high electric conductivity, as supported by molecular dynamics simulations.
Topics & Concepts
AntiaromaticityDimension (graph theory)NanotechnologyChemistryMaterials scienceMathematicsPure mathematicsAromaticityOrganic chemistryMoleculeSynthesis and Properties of Aromatic CompoundsPorphyrin and Phthalocyanine ChemistryOrganic Electronics and Photovoltaics