A three-dimensional energetic coordination compound (BLG-1) with excellent initiating ability for lead-free primary explosives
Guorong Lei, Wenchuan Cheng, Zujia Lu, Tonglai Zhang, Zhimin Li, Jianguo Zhang
Abstract
) among N-rich copper bromate ECCs. More importantly, a primary charge of BLG-1 as little as 3 mg could reliably detonate compressed RDX, and 1 mg could detonate CL-20. These incredible values indicated that BLG-1 had an ultra-powerful initiating ability far superior to that of previously reported primary explosives. BLG-1 had improved mechanical sensitivities (IS: 13 J; FS: 1 N) and electrostatic sensitivity (EDS: 240 mJ) compared with those of the typical lead-based primary explosive, lead azide (IS: 4J; FS: 0.75N; EDS: 5 mJ). In particular, BLG-1 had a low laser-initiation threshold of 13 mJ at 808 nm, suggesting that it could serve as a laser-ignitable primary explosive. This work suggests that BLG-1 is a promising candidate with engreat practical application prospects for lead-free primary explosives.