Control of photoluminescence properties by tailored supramolecular matrices
Frank Würthner, Mahesh Hariharan
Abstract
Photoluminescence (PL) is a property of great interest in science and technology. Here we review recent approaches for the control of fluorescence and phosphorescence by tailored supramolecular environments. Taking recent examples from solid-state materials as applied in organic light-emitting diodes (OLEDs), supramolecular complexes, cyclophanes, foldamers, and protein–dye complexes, as well as DNA and RNA aptamers, we showcase how specific ‘smart' matrices can modulate PL properties including brightness, quantum yield, wavelength, and lifetime. From the examples collected in this review it becomes evident that, by means of an advanced understanding of specific interactions of chromophores with the surrounding matrix, relevant processes in the excited state can be controlled in a desired way, leading to improved light-emitting materials.