Electrooxidative <i>o</i>-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature
Long Yang, Becky Bongsuiru Jei, Alexej Scheremetjew, Binbin Yuan, A. Claudia Stückl, Lutz Ackermann
Abstract
Copper-catalyzed electrochemical cage C–H chalcogenation of o -carboranes has been realized to enable the synthesis of various cage C-sulfenylated and C-selenylated o -carboranes.
Topics & Concepts
CageChemistryCarboraneCatalysisCopperStereochemistryMedicinal chemistryOrganic chemistryMathematicsCombinatoricsBoron Compounds in ChemistryRadioactive element chemistry and processingCrystallography and molecular interactions