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Synthesis of rare-earth metal complexes with a morpholine-functionalized β-diketiminato ligand and their catalytic activities towards C–O and C–N bond formation

Xiancui Zhu, Jinqiang He, Yuanqing Yang, Shuangliu Zhou, Yun Wei, Shaowu Wang

2022Dalton Transactions10 citationsDOI

Abstract

Novel rare-earth-metal-complexes catalyzed the C–O and C–N bond construction through alcoholysis of isothiocyanates and aminolysis of epoxides.

Topics & Concepts

MorpholineCatalysisRare earthChemistryLigand (biochemistry)MetalPhotochemistryInorganic chemistryMedicinal chemistryOrganic chemistryMineralogyReceptorBiochemistryCarbon dioxide utilization in catalysisCoordination Chemistry and OrganometallicsChemical Synthesis and Reactions
Synthesis of rare-earth metal complexes with a morpholine-functionalized β-diketiminato ligand and their catalytic activities towards C–O and C–N bond formation | Litcius