Polyoxometalate-based supramolecular porous frameworks with dual-active centers towards highly efficient synthesis of functionalized <i>p</i>-benzoquinones
Shenzhen Chang, Yanhong Chen, Haiyan An, Qingshan Zhu, Huiyun Luo, Yao-Hui Huang
Abstract
Two POM-based supramolecular porous frameworks were prepared, which can efficiently oxidize substituted phenols and even alkoxybenzenes to corresponding p -benzoquinones under mild conditions.
Topics & Concepts
PolyoxometalateSupramolecular chemistryPorosityPhenolsChemistryDual (grammatical number)Combinatorial chemistryOrganic chemistryCatalysisMoleculeLiteratureArtPolyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and Reactions