X-ray diffraction and equation of state of the C–S–H room-temperature superconductor
Anmol Lamichhane, Ravhi Kumar, Muhtar Ahart, Nilesh P. Salke, Nathan Dasenbrock-Gammon, Elliot Snider, Yue Meng, Barbara Lavina, Stella Chariton, Vitali B. Prakapenka, Maddury Somayazulu, Ranga P. Dias, Russell J. Hemley
Abstract
X-ray diffraction indicates that the structure of the recently discovered carbonaceous sulfur hydride (C–S–H) room-temperature superconductor is derived from previously established van der Waals compounds found in the H2S–H2 and CH4–H2 systems. Crystals of the superconducting phase were produced by a photochemical synthesis technique, leading to the superconducting critical temperature Tc of 288 K at 267 GPa. X-ray diffraction patterns measured from 124 to 178 GPa, within the pressure range of the superconducting phase, are consistent with an orthorhombic structure derived from the Al2Cu-type determined for (H2S)2H2 and (CH4)2H2 that differs from those predicted and observed for the S–H system at these pressures. The formation and stability of the C–S–H compound can be understood in terms of the close similarity in effective volumes of the H2S and CH4 components, and denser carbon-bearing S–H phases may form at higher pressures. The results are crucial for understanding the very high superconducting Tc found in the C–S–H system at megabar pressures.