Solvate sponge crystals of (DMF)<sub>3</sub>NaClO<sub>4</sub>: reversible pressure/temperature controlled juicing in a melt/press-castable sodium-ion conductor
Prabhat Prakash, Shylendran Ardhra, Birane Fall, Michael J. Zdilla, Stephanie L. Wunder, Arun Venkatnathan
Abstract
ion leads to the conversion of the 3 : 1 stoichiometry to a 2 : 1 stoichiometry. The simulations reveal the anisotropic nature of pressure induced stoichiometric conversion. The results provide molecular level understanding of a solvate sponge crystal with novel and desirable physical castability properties for device fabrication.
Topics & Concepts
StoichiometryIonInorganic chemistrySodiumChemistryCrystallographyMaterials scienceAnalytical Chemistry (journal)Physical chemistryOrganic chemistryLuminescence and Fluorescent MaterialsMolecular Sensors and Ion DetectionMetal-Organic Frameworks: Synthesis and Applications